AbstractsChemistry
Liquid-Phase Epitaxial Growth of Highly Oriented and Crystalline MOF Thin Films: Post-Synthetic Modification and Different Applications
| Institution: | Universität Karlsruhe |
|---|---|
| Department: | |
| Year: | 2015 |
| Record ID: | 1104186 |
| Full text PDF: | http://digbib.ubka.uni-karlsruhe.de/volltexte/documents/3422938 |
Abstract
The studies for this PhD thesis showed the preparation, characterization and application of new-type surface-mounted metal-organic frameworks (SURMOFs). The aims were to: (1) heteroepitaxially grow MOF-on-MOF multilayer systems with huge lattice mismatch; (2) modify azide-based SURMOFs using alkyne-azide click chemistry; (3) chemically pattern SURMOFs using postsynthetic modification (PSM); (4) engineer UHM-3 SURMOFs with quantitative Cu(I) defects using postsynthetic thermal treatment.
