AbstractsEarth & Environmental Science

The electrical resistivity of the Posidonia black shale

by Filipe Jorge Santos Ferreira Adao

Institution: Freie Universität Berlin
Department: FB Geowissenschaften
Degree: PhD
Year: 2015
Record ID: 1110166
Full text PDF: http://edocs.fu-berlin.de/diss/receive/FUDISS_thesis_000000098701


I carried out a magnetotelluric field survey in the southeastern area of the Lower Saxony Basin, in Germany. Eighty-three magnetotelluric stations were deployed along a SW-NE, sixty-three kilometre long profile. The main goals of the survey were of testing this geophysical method for imaging the regional Posidonia black shale formation and evaluating the influence of thermal maturity in its electrical resistivity. The acquired data were highly affected by cultural noise. For this reason, I discarded the southern profile section between stations one and twenty-seven. However, data processing was successful for the majority of stations between twenty-eight and eighty-three. The corresponding geo-electric strike estimates point to a predominantly E-W direction, in accordance with regional geology and major faults. Two-dimensional magnetotelluric inversion results of the acquired data show a series of electrically conductive structures which correlate with brine saturated sediments but also with deeper, meta-anthracitic/graphitized Carboniferous coals. However, none of these structures could be directly related with the Posidonia black shale, which appears to be generally electrically resistive due to its low thermal maturity and, therefore, very difficult to resolve with the magnetotelluric method. Besides the magnetotelluric experiment, I made a series of laboratory measurements of electrical resistivity on a set of Posidonia black shale samples from the Hils syncline structure found in the Lower Saxony basin. The corresponding rock samples were collected in shallow wells named Wickensen, Harderode and Haddessen. These three wells show immature, oil and gas thermal maturities, respectively. Results showed that the Posidonia black shale samples are electrically resistive, when measured in dry conditions. Furthemore, electrical resistivity is consistently higher when measured against rock bedding, which indicates that the Posidonia black shale is heterogeneous and electrically anisotropic. I observed no direct correlation between electrical resistivity and thermal maturity: the Harderode samples showed the highest electrical resistivity, whilst the Haddessen samples showed the lowest. This was an unexpected result because the increase of thermal maturity between Wickensen and Haddessen contributed to the aromatization of the organic carbon in the Posidonia black shale. Consequently, this effect should have contributed to a constant decrease of electrical resistivity in the Posidonia black shale between Wickensen and Haddessen. An ineffective drying process and the presence of moisture could have been the reasons for the observed trend of electrical resistivity. I tested the dependence of electrical resistivity of the Posidonia black shale samples on water content by saturating them with distilled and saline water solutions. The saturation process led to a constant and significant decrease of electrical resistivity of the experimented samples. Moreover, increasing salinity corresponded to higher drops in electrical…