Hydrogen physisorptive storage in metal-organicframeworks (MOFs)

by author] [No

Institution: University of Pretoria
Year: 2016
Keywords: UCTD
Posted: 02/05/2017
Record ID: 2109452
Full text PDF: http://hdl.handle.net/2263/56105


Generation of power from fossil fuels produces large amounts of carbon dioxide which is a major contributor to global warming and many other environmental problems. Alternative sources of energy are available but fossil fuels remain the main source of energy for on-board energy generation. One alternative source that has gained great popularity in recent years has been hydrogen. The characteristics which it possesses make it an ideal alternative to fossil fuels for on-board energy generation and also for stationary (portable) power applications. Widespread use of hydrogen as an energy carrier can only be realised once a reliable storage method which is safe and affordable becomes available. Such a storage medium should have sufficient hydrogen storage capacity, fast kinetics, and be capable of delivering hydrogen gas to a fuel cell at ambient or near-ambient conditions. This study investigated the storage of hydrogen using metal-organic frameworks (MOFs). MOFs are a class of porous inorganic-organic crystalline materials that store hydrogen by adsorption. What makes MOFs such an attractive option for hydrogen storage is that they have exceptionally high surface areas and porosity, as well as tunable pore sizes and internal surfaces. MOFs have provided successful hydrogen storage at cryogenic temperatures (77 K) and a major challenge is to reach high storage capacities at ambient temperatures and acceptable pressures. The HySA Infrastructure Centre of Competence (CoC), one of three centres of competence established by the Department of Science and Technology (DST) to implement the National Hydrogen and Fuel Cells Strategy, is tasked with R&D on hydrogen generation, storage and distribution. A major part of the hydrogen storage R&D is the development of MOFs for hydrogen storage with the ultimate aim of using the developed MOFs for practical applications, including fuel cell vehicles and portable power applications, using metals that promote the beneficiation of South African mineral resources. The MOFs that were investigated in this study are zinc-based MOF (Zn-MOF, MOF-5), zirconium-based MOF (Zr-MOF, UiO-66) and chromium-based MOF (Cr-MOF, MIL-101). These MOFs were chosen because they were envisaged as potential hydrogen storage options. MOF-5 in particular was seen as an ideal starting point for this study as it has been reported to have high surface area, permanent porosity, good thermal stability and a high synthetic yield. In addition, MOF-5 is amongst the most widely investigated MOFs for hydrogen storage. In this study, MOF-5 with high crystallinity and good morphology was synthesised using either N,N-diethylformamide (DEF) or dimethylformamide (DMF) as solvent. As DMF is a cheaper solvent than DEF the synthesis conditions were optimised for the DMF-synthesised MOF-5 and detailed analyses performed. It was discovered at some point that MOF-69c was produced as a product instead of MOF-5. Successful transition from MOF-69c to MOF-5 was achieved by employing a simple heat treatment. Due to the moisture… Advisors/Committee Members: Crouse, Philippus L (advisor), Ren, Jianwei (advisor), Langmi, Hendrietta W (advisor).