A structural thermodynamic and equilibrium study of chiral pendant arm triaza macrocyclic ligand complexes: towards the formation of metal-ion activated molecular receptors : a thesis submitted for the degree of Doctor of Philosophy at the University of Adelaide (Faculty of Science) / by Jennifer Megan Weeks.
Institution: | University of Adelaide |
---|---|
Department: | |
Year: | 2000 |
Keywords: | Ligands.; Monovalent cations.; Metal ions Spectra.; Diazo reaction. |
Record ID: | 1032301 |
Full text PDF: | http://hdl.handle.net/2440/19622 |
Addresses the structural, equilibrium and thermodynamic aspects of pendant arm donor triaza macrocyclic ligands and their alkali metal and zinc complexes. Involves ab initio molecular modelling, x-ray crystallographic studies, potentiometric stability constant determinations and NMR kinetic studies.