Transition Metal Oxide Nanoparticles Anchored Nanocarbon Hybrid Foam for High Performance Electrochemical Energy Storage Applications

by Wei Wang

Institution: University of California – Riverside
Department: Electrical Engineering
Year: 2014
Keywords: Electrical engineering; Energy; energy storage; foam; nanocarbon; pseudocapacitor; supercapacitor; transition metal oxide
Record ID: 2033146
Full text PDF: http://www.escholarship.org/uc/item/7cf9s1xq


In real life applications, supercapacitors (SCs) often can only be used as part of a hybrid system together with other high energy storage devices due to their relatively lower energy density in comparison to other types of energy storage devices, such as batteries and fuel cells. Increasing the energy density of SCs will have a huge impact on the development of future energy storage devices by broadening the area of application for SCs. Here, we report a simple and scalable way of preparing a three-dimensional (3D) sub-5 nm hydrous ruthenium oxide (RuO2) anchored graphene and CNT hybrid foam (RGM) architecture for high-performance supercapacitor electrodes. This RGM architecture demonstrates a novel graphene foam conformally covered with hybrid networks of RuO2 nanoparticles and anchored CNTs. SCs based on RGM show superior gravimetric and per-area capacitive performance (specific capacitance: 502.78 F g-1, areal capacitance: 1.11 F cm-2) at the same time which leads to a exceptionally high energy density of 39.28 Wh kg-1 and power density of 128.01 kW kg-1. The electrochemical stability, excellent capacitive performance, and the ease of preparation suggest this RGM system is promising for future energy storage applications.