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Abstracts Chemistry
by Jacob Paul Hieble
| Institution: | North Texas State University |
|---|---|
| Department: | |
| Degree: | |
| Year: | 1971 |
| Keywords: | Alkylhaloketene-cyclopentadiene.; tropolone; dichloroketene-cyclopentadiene adduct |
| Posted: | |
| Record ID: | 1487489 |
| Full text PDF: | http://digital.library.unt.edu/ark:/67531/metadc164519/ |
Abstract
This research is concerned with determining whether the previously reported synthesis of tropolone by the solvolysis of the dichloroketene-cyclopentadiene adduct in sodium acetate and acetic acid could be used to prepare 2-alkyltropones from the adducts of alkylhaloketenes and cyclopentadiene. The information obtained from these rearrangements could be useful in determining the mechanism of the ring expansion of halogenated ketene-cyclopentadiene adducts to tropone derivatives.
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