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Characterization of bonding differences by advanced synchrotron based X-ray spectroscopy

by Tim Prüßmann

Institution:	Universität Karlsruhe
Year:	2016
Posted:	02/05/2017
Record ID:	2129128
Full text PDF:	http://digbib.ubka.uni-karlsruhe.de/volltexte/documents/3802298

Abstract

The present PhD thesis demonstrates differences in relative electronic densities and mixing of metal with ligand valence orbitals between the n-Pr-BTP ligand, the [Ln(n-Pr-BTP)3](OTf)3 and [An(n-Pr-BTP)3](OTf)3 complexes using N K edge XANES spectroscopy, Ln/An L3 edge HR-XANES spectroscopy and quantum chemical calculations. A spectrometer for high-energy resolution X-ray emission spectroscopy and a liquid cell for non-resonant inelastic X-ray scattering were designed, built and commissioned.